A Priori Estimation of the Resolvent on Approximation of Born-Oppenheimer

Abstract

In this study, we estimate the resolvent of the two bodies Shrodinger operator perturbed by a potential of Coulombian type on Hilbert space when h tends to zero. Using the Feschbach method, we first distorted it and then reduced it to a diagonal matrix. We considered a case where two energy levels cross in the classical forbidden region. Under the assumption that the second energy level admits a non degenerate point well and virial conditions on the others levels, a good estimate of the resolvent were observed.